MgF3 rather than by phosphoranes
نویسندگان
چکیده
Department of Molecular Biology and Biotechnology, University of Sheffield, Sheffield S10 2TN, United Kingdom; Structural Biology Group, European Synchrotron Radiation Facility, 6 rue Jules Horowitz, F-38043 Grenoble, France; Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588; Centre for Chemical Biology, Department of Chemistry, University of Sheffield, Sheffield S3 7HF, United Kingdom; and Faculty of Life Sciences and Manchester Interdisciplinary Biocentre, University of Manchester, Manchester, M1 7DN, United Kingdom
منابع مشابه
Synthesis and application of a bidentate ligand based on decafluoro-3-phenyl-3-pentanol: steric effect of pentafluoroethyl groups on the stereomutation of O-equatorial C-apical spirophosphoranes.
1,1,1,2,2,4,4,5,5,5-Decafluoro-3-phenyl-3-pentanol was prepared by a Cannizzaro-type disproportionation reaction, and the dimetallated compound was used as a bidentate ligand, which is bulkier than the Martin ligand (1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanol). A P-H spirophosphorane was synthesized by utilizing the new bidentate ligand, and the structure of the product was essentially the same...
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